PUBLICATIONS

BOOK CHAPTERS

1  Victor N. Nemykin and Eugenii A. Lukyanets, "The key role of the peripheral substituents in the chemistry of phthalocyanines", in: Handbook of Porphyrin Science , K. M. Kadish, K. M. Smith and R. Guilard (Eds.); World Scientific: Singapore, 2010 , Vol 3 ., pp 1 - 323 .

2  Victor N. Nemykin and Paul Kiprof, "Preparation, UV-Vis and MCD spectroscopy, and molecular modeling of zinc phthalocyanine: confirmation of degeneracy of the first excited state", in: The Integrated Approach to Chemistry Laboratory , P. Basu and M. Johnson (Eds).; DEStech Publications, Inc.: Lancaster , PA , 2009 ; pp 95 – 105.

3  Victor N. Nemykin, "Three or Four Heteroatoms including at least One Other Element", in: Comprehensive Heterocyclic Chemistry III , A. R. Katritzky , C. A. Ramsden, E. F. V. Scriven and R. J. K. Taylor (Eds.); Elsevier: Oxford , 2008 ; Vol. 6 , pp 691 - 738.

 

PREFACE

1. Nemykin, V. N. "Preface for special issue" J. Porphyrins Phthalocyanines 2013 , 17 (8-9), i-ii.

 

RESEARCH PAPERS ( 199 total; h-index = 36; i-10 index = 102 )

  Research Papers since at University of Manitoba (2016 - current)

•  Majeed, S. A.; Ghazal, B.; Nevonen, D. E.; Goff, P. C.; Blank, D. A.; Nemykin, V. N.; Makhseed, S. “Evaluation of the intramolecular charge-?transfer properties in solvatochromic and electrochromic zinc octa(carbazolyl)?phthalocyanines” Inorg. Chem. 2017 , 56 , 11640-11653.

•  Cheadle, C.; Ratcliff, J.; Berezin, M. Y.; Pal'shin, V.; Nemykin, V.; Gerasimchuk, N. “Shortwave infrared luminescent Pt-?nanowires: mechanistic study of emission in solution and solid state” Dalton Trans. 2017 , DOI: 10.1039/C7DT02317K, Ahead of Print .

•  Zatsikha, Y. V.; Nemez, D. B.; Davis, R. L.; Singh, S.; Herbert, D. E.; King, A. J.; Ziegler, C. J.; Nemykin, V. N. “Testing the Limits of the BOPHY Platform: Preparation, Characterization, and Theoretical Modeling of BOPHYs and Organometallic BOPHYs with Electron-?Withdrawing Groups at ß-?Pyrrolic and Bridging Positions” Chem. Eur. J. 2017 , DOI: 10.1002/chem.201703947, Ahead of Print . ( this paper was highlighted on a cover page )

•  Yoshimura, A.; Nguyen, K.C.; Nemykin, V.N.; Zhdankin, V.V. “Preparation, Structure, and Oxidative Reactivity of (Dichloroiodo)pyridines: Recyclable Hypervalent Iodine Reagents” ARKIVOC 2018 , just accepted .

•  Baba, T.; Takahashi, S.; Kambara, Y.; Yoshimura, A.; Nemykin, V.N.; Zhdankin, V.V.; Saito, A. “Development of Imino-? 3 -iodanes with Improved Reactivity for Metal-Free [2+2+1] Cycloaddition-Type Reactions” Adv. Synth. Cat. 2017 , just accepted , DOI 10.1002/adsc.201700934.

•  Shaw, J. L.; Doble, S. J.; Stewart, J.; Nemykin, V. N. “Charged and confused: Meso-?tetrakis(p-?methoxycarbonyl-?phenyl) N-?confused porphyrin as a precursor to water soluble variants” J. Porphyrins Phthalocyanines 2017 , 21 , 287-294.

•  Nemykin, V. N.; Blesener, T. S.; Ziegler, C. J. “Photophysics, redox processes, and electronic structures of ferrocenyl-containing BODIPYs, aza-BODIPYs, BOPHYs, transition-metal dipyrromethenes and aza-dipyrromethenes” Macroheterocycles , 2017 , 10(1), 9-26. ( this paper was highlighted on a cover page )

•  Zatsikha, Y. V.; Didukh, N. O.; Nemez, D.; Schlachter, A. C.; Karsenti, P.-L.; Kovtun, Y. P.; Harvey, P. D.; Nemykin, V. N. “Ferrocene-?BODIPY merocyanine dyads: new NIR absorbing platforms with optical properties susceptible to protonation” Chem. Commun. 2017 , 53 , 7612-7615.

•  Makarova, E. A.; Zatsikha, Y. V.; Newman, K. M. E.; Paidi, V. K.; Beletsky, V. A.; van Lierop, J.; Lukyanets, E. A.; Nemykin, V. N. “Direct Synthesis of an Unprecedented Stable Radical of Nickel(II) 3,?5-?Bis(dimedonyl)?azadiisoindomethene with Strong and Narrow Near-?Infrared Absorption at ? ~ 1000 nm” Inorg. Chem. 2017 , 56 , 6052-6055.

•  Doble, S.; Osinski, A. J.; Holland, S. M.; Fisher, J. M.; Geier, G. R.; Belosludov, R. V.; Ziegler, C. J.; Nemykin, V. N. “Magnetic Circular Dichroism of Transition-?Metal Complexes of Perfluorophenyl-?N-?Confused Porphyrins: Inverting Electronic Structure through a Proton” J. Phys. Chem. A 2017 , 121 , 3689-3698.

•  Erickson, N. R.; Holstrom, C. D.; Rhoda, H. M.; Rohde, G. T.; Zatsikha, Y. V.; Galloni, P.; Nemykin, V. N. “Tuning Electron-?Transfer Properties in 5,?10,?15,?20-?Tetra(1'-?hexanoylferrocenyl)?porphyrins as Prospective Systems for Quantum Cellular Automata and Platforms for Four-?Bit Information Storage” Inorg. Chem. 2017 , 56 , 4717-4728.

•  Kawamata, M.; Sugai, T.; Minoura, M.; Maruyama, Y.; Furukawa, K.; Holstrom, C.; Nemykin, V. N.; Nakano, H.; Matano, Y. “Nitrogen-?Bridged Metallodiazaporphyrin Dimers: Synergistic Effects of Nitrogen Bridges and meso-?Nitrogen Atoms on Structure and Properties” Chem. Asian J. 2017 , 12 , 816-821.

•  Zatsikha, Y. V.; Holstrom, C. D.; Chanawanno, K.; Osinski, A. J.; Ziegler, C. J.; Nemykin, V. N. “Observation of the Strong Electronic Coupling in Near-?Infrared-?Absorbing Tetraferrocene aza-?Dipyrromethene and aza-?BODIPY with Direct Ferrocene-?a- and Ferrocene-?ß-?Pyrrole Bonds: Toward Molecular Machinery with Four-?Bit Information Storage Capacity” Inorg. Chem. 2017 , 56 , 991-1000.

•  Cidlina, A.; Miletin, M.; Fathi-Rasekh, M.; Nemykin, V. N.; Zimcik, P.; Novakova, V. “OFF-?ON-?OFF Red-?Emitting Fluorescent Indicators for a Narrow pH Window” Chem. Eur. J. 2017 , 23 , 1795-1804. ( this paper was highlighted on a cover page and covered by Wiley )

•  Yoshimura, A.; Klasen, S. C.; Shea, M. T.; Nguyen, K. C.; Rohde, G. T.; Saito, A.; Postnikov, P. S.; Yusubov, M. S.; Nemykin, V. N.; Zhdankin, V. V. “Preparation, Structure, and Reactivity of Pseudocyclic Benziodoxole Tosylates: New Hypervalent Iodine Oxidants and Electrophiles” Chem. Eur. J. 2017 , 23 , 691-695.

•  Zatsikha, Y. V.; Didukh, N. O.; Blesener, T.; Kayser, M. P.; Kovtun, Y. P.; Blank, D. A.; Nemykin, V. N. “Preparation, Characterization, Redox, and Photoinduced Electron-?Transfer Properties of the NIR-?Absorbing N-?Ferrocenyl-?2-?Pyridone BODIPYs” Eur. J. Inorg. Chem. 2017 , (2), 318-324. ( invited paper for special issue )

•  Didukh, N. O.; Zatsikha, Y. V.; Rohde, G. T.; Blesener, T. S.; Yakubovskyi, V. P.; Kovtun, Y. P.; Nemykin, V. N. “NIR absorbing diferrocene-containing meso-cyano-BODIPY with a UV-Vis-NIR spectrum remarkably close to that of magnesium tetracyanotetraferrocenyltetraazaporphyrin” Chem. Commun. 2016 , 52 , 11563-11566.

•  Li, Y.; Rhoda, H. M.; Wertish, A. M.; Nemykin, V. N. “Organometallic pyrene-containing porphyrins: Synthesis, characterization, and non-covalent interactions with C 60 fullerenes” J. Porphyrins Phthalocyanines 2016 , 20 , 1098-1113 ( invited paper for special issue ).

•  Chanawanno, K.; Holstrom, C.; Nemykin, V. N.; Herrick, R. S.; Ziegler, C. J. “New 1,1'-Ferrocene Bis(sulfonyl) Reagents” ChemistrySelect 2016 , 1 , 6438-6441.

•  Osinski, A. J.; Blesener, T.; Hasheminasab, A.; Holstrom, C.; Nemykin, V. N.; Herrick, R. S.; Ziegler, C. J. “Re(CO) 3 -Templated Synthesis of Semihemiporphyrazines” Inorg. Chem. 2016 , 55 , 12527-12530.

•  Dudkin, S. V.; Erickson, N. R.; Vologzhanina, A. V.; Novikov, V. V.; Rhoda, H. M.; Holstrom, C. D.; Zatsikha, Y. V.; Yusubov, M. S.; Voloshin, Y. Z.; Nemykin, V. N. “Preparation, X-ray Structures, Spectroscopic, and Redox Properties of Di- and Trinuclear Iron-Zirconium and Iron-Hafnium Porphyrinoclathrochelates” Inorg. Chem. 2016 , 55 , 11867-11882.

•  Chanawanno, K.; Holstrom, C.; Crandall, L. A.; Dodge, H.; Nemykin, V. N.; Herrick, R. S.; Ziegler, C. J. “The synthesis and structures of 1,1'-bis(sulfonyl)ferrocene derivatives” Dalton Trans. 2016 , 45 , 14320-14326.

•  Rhoda, H. M.; Akhigbe, J.; Ogikubo, J.; Sabin, J. R.; Ziegler, C. J.; Bruckner, C.; Nemykin, V. N. “Magnetic Circular Dichroism Spectroscopy of meso-Tetraphenylporphyrin-Derived Hydroporphyrins and Pyrrole-Modified Porphyrins” J. Phys. Chem. A 2016 , 120 , 5805-5815.

•  Yoshimura, A.; Nguyen, K. C.; Klasen, S. C.; Postnikov, P. S.; Yusubov, M. S.; Saito, A.; Nemykin, V. N.; Zhdankin, V. V. “Hypervalent Iodine-Catalyzed Synthesis of 1,2,4-Oxadiazoles from Aldoximes and Nitriles” Asian J. Org. Chem. 2016 , 5 , 1128-1133.

•  Rhoda, H. M.; Kayser, M. P.; Wang, Y.; Nazarenko, A. Y.; Belosludov, R. V.; Kiprof, P.; Blank, D. A.; Nemykin, V. N. “Tuning Up an Electronic Structure of the Subphthalocyanine Derivatives toward Electron-Transfer Process in Noncovalent Complexes with C60 and C70 Fullerenes: Experimental and Theoretical Studies” Inorg. Chem. 2016 , 55 , 9549-9563 ( editor's choice; front cover ).

•  Chanawanno, K.; Rhoda, H. M.; Hasheminasab, A.; Crandall, L. A.; King, A. J.; Herrick, R. S.; Nemykin, V. N.; Ziegler, C. J. “Using hydrazine to link ferrocene with Re(CO) 3 : A modular approach” J. Organomet. Chem. 2016 , 818 , 145-153.

•  Anderson, D. R.; Solntsev, P. V.; Rhoda, H. M.; Nemykin, V. N. “How big is big? Separation by conventional methods, X-ray and electronic structures of positional isomers of bis-tert-butylisocyano adduct of 2(3),9(10),16(17),23(24)-tetrachloro-3(2),10(9),17(16),24(23)-tetra(2,6-di-iso-propylphenoxy)-phthalocyaninato iron(II) complex” J. Porphyrins Phthalocyanines 2016 , 20 , 337-351 ( invited paper for special issue ).

•  Pushkarev, V. E.; Tomilova, L. G.; Nemykin, V. N. “Historic overview and new developments in synthetic methods for preparation of the rare-earth tetrapyrrolic complexes” Coord. Chem. Rev. 2016 , 319 , 110-179 ( invited review ).

•  Crandall, L. A.; Rhoda, H. M.; Nemykin, V. N.; Ziegler, C. J. “Boron templated synthesis of a BODIPY analogue from a phthalocyanine precursor” New J. Chem. 2016 , 40 , 5675-5678.

•  Belosludov, R. V.; Rhoda, H. M.; Zhdanov, R. K.; Belosludov, V. R.; Kawazoe, Y.; Nemykin, V. N. “Conceptual design of tetraazaporphyrin- and subtetraazaporphyrin-based functional nanocarbon materials: electronic structures, topologies, optical properties, and methane storage capacities” Phys. Chem. Chem. Phys. 2016 , 18 , 13503-13518.

•  Solntsev, P. V.; Anderson, D. R.; Rhoda, H. M.; Belosludov, R. V.; Fathi-Rasekh, M.; Maligaspe, E.; Gerasimchuk, N. N.; Nemykin, V. N. “Initial Report on Molecular and Electronic Structure of Spherical Multiferrocenyl/tin(IV) (Hydr)oxide [(FcSn) 12 O 14 (OH) 6 ]X 2 Clusters” Crystal Growth Design 2016 , 16 , 1027-1037. . Research papers published from the University of Minnesota - Duluth

•  Nemykin, V. N.; Dudkin, S. V.; Fathi-Rasekh, M.; Spaeth, A. D.; Rhoda, H. M.; Belosludov, R. V.; Barybin, M. V. “Probing Electronic Communications in Heterotrinuclear Fe-?Ru-?Fe Molecular Wires Formed by Ruthenium(II) Tetraphenylporphyrin and Isocyanoferrocene or 1,?1'-?Diisocyanoferrocene Ligands” Inorg. Chem. 2015 , 54 , 10711-10724.

•  Rhoda, H. M.; Chanawanno, K.; King, A. J.; Zatsikha, Y. V.; Ziegler, C. J.; Nemykin, V. N. “Unusually Strong Long-?Distance Metal-?Metal Coupling in Bis(ferrocene)?-?Containing BOPHY: An Introduction to Organometallic BOPHYs” Chem. Eur. J. 2015 , 21 , 18043-18046.

•  Hasheminasab, A.; Rhoda, H. M.; Crandall, L. A.; Ayers, J. T.; Nemykin, V. N.; Herrick, R. S.; Ziegler, C. J. “Hydrazine-?mediated strongly coupled Re(CO)? 3 dimers” Dalton Trans. 2015 , 44 , 17268-17277.

•  Zatsikha, Y. V.; Maligaspe, E.; Purchel, A. A.; Didukh, N. O.; Wang, Y.; Kovtun, Y. P.; Blank, D. A.; Nemykin, V. N. "Tuning electronic structure, redox, and photophysical properties in asymmetric NIR- absorbing organometallic BODIPYs" Inorg. Chem. 2015 , 54 , 7915-7928.

•  Mogesa, B.; Perera, E.; Rhoda, H. M.; Gibson, J. K.; Oomens, J.; Berden, G.; van Stipdonk, M. J.; Nemykin, V. N.; Basu, P. "Solution, Solid, and Gas Phase Studies on a Nickel Dithiolene System: Spectator Metal and Reactor Ligand" Inorg. Chem. 2015 , 54 , 7703-7716 .

•  Novakova, V.; Reimerova, P.; Svec, J.; Suchan, D.; Miletin, M.; Rhoda, H. M.; Nemykin, V. N.; Zimcik, P. "Systematic investigation of phthalocyanines, naphthalocyanines, and their aza-analogues. Effect of the isosteric aza-replacement in the core" Dalton Trans. 2015 , 44 , 13220-13233.

•  Yusubov, M. S.; Svitich, D. Yu.; Yoshimura, A.; Kastern, B. J.; Nemykin, V. N.; Zhdankin, V. V. Preparation, X-?ray Structure, and Reactivity of Triisopropylsilyl-?Substituted Aryl-?iodonium Salts Eur. J. Org. Chem. 2015 , (22) , 4831-4834.

•  Postnikov, P. S.; Guselnikova, O. A.; Yusubov, M. S.; Yoshimura, A.; Nemykin, V. N.; Zhdankin, V. V. "Preparation and X-?ray Structural Study of Dibenziodolium Derivatives" J. Org. Chem. 2015 , 80 , 5783-5788.

•  Rhoda, H. M.; Crandall, L. A.; Geier III, G. R.; Ziegler, C. J.; Nemykin, V. N. "Combined MCD/DFT/TDDFT Study of the Electronic Structure of Axially Pyridine Coordinated Metallocorroles" Inorg. Chem. 2015 , 54 , 4652-4662 .

•  Xu, Z.; Gao, F.; Makarova, E. A.; Heikal, A. A.; Nemykin, V. N. "Energy Transfer from Colloidal Quantum Dots to Near-?Infrared-?Absorbing Tetraazaporphyrins for Enhanced Light Harvesting" J. Phys. Chem. C 2015 , 119 , 9754-9761 .

•  Yoshimura, A.; Nguyen, K. C.; Klasen, S. C.; Saito, A.; Nemykin, V. N.; Zhdankin, V. V."Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent" Chem. Commun. 2015 , 51 , 7835-7838.

•  Maligaspe, E.; Pundsack, T. J.; Albert, L. M.; Zatsikha, Y. V.; Solntsev, P. V.; Blank, D. A.; Nemykin, V. N. "Synthesis and Charge-?Transfer Dynamics in a Ferrocene-?Containing Organoboryl aza-?BODIPY Donor-?Acceptor Triad with Boron as the Hub" Inorg. Chem. 2015 , 54 , 4167-4174.

•  Vecchi, A.; Erickson, N. R.; Sabin, J. R.; Floris, B.; Conte, V.; Venanzi, M.; Galloni, P.; Nemykin, V. N. “Electronic properties of mono-substituted tetraferrocenyl porphyrins in solution and on gold surface: assessment of the influencing factors for photoelectrochemical applications” Chem. Eur. J. 2015 , 21 , 269-279 .

•  Vecchi, A.; Galloni, P.; Floris, B.; Dudkin, S. V.; Nemykin, V. N. "Metallocenes meet porphyrinoids: Consequences of a "fusion"" Coord. Chem. Rev. 2015 , 291 , 95-171.

•  Yoshimura, A.; Koski, S. R.; Fuchs, J. M.; Saito, A.; Nemykin, V. N.; Zhdankin, V. V. "Saccharin-Based µ-Oxo Imidoiodane: A Readily Available and Highly Reactive Reagent for Electrophilic Amination" Chem. Eur. J. 2015 , 21 , 5328-5331.

•  Nemykin, V. N.; Makarova, E. A.; Erickson, N. R.; Solntsev, P. V. “Coupling ferrocene to brominated tetraazaporphyrin: exploring an alternative synthetic pathway for preparation of ferrocene-containing tetraazaporphyrins” Turk. J. Chem. 2014 , 38 , 1027-1045 ( invited paper for special issue ).

•  Nemykin, V. N.; Makarova, E. A.; Grosland, J. O.; Dudkin, S. V.; Dennison, R.; Purchel, A. A. “Tuning the near-IR energy and redox potentials of magnesium tetra(ferrocenyl)tetraazaporphyrins” J. Porphyrins Phthalocyanines 2014 , 18 , 792-803 ( invited paper for special issue ).

•  Yusubov, M. S.; Celik, C.; Geraskina, M. R.; Yoshimura, A.; Zhdankin, V. V.; Nemykin, V. N. “Binuclear iron(III) octakis(perfluorophenyl)?tetraazaporphyrin µ-?oxodimer: a highly efficient catalyst for biomimetic oxygenation reactions” Tetr. Lett. 2014 , 55 , 5687-5690.

•  Maligaspe, E.; Hauwiller, M. R.; Zatsikha, Y. V.; Hinke, J. A.; Solntsev, P. V.; Blank, D. A.; Nemykin, V. N. "Redox and Photoinduced Electron-?Transfer Properties in Short Distance Organoboryl Ferrocene-?Subphthalocyanine Dyads" Inorg. Chem. 2014 , 53 , 9336-9347.

•  Sun, B.; Ou, Z.; Meng, D.; Fang, Y.; Song, Y.; Zhu, W.; Solntsev, P. V.; Nemykin, V. N.; Kadish, K. M. "Electrochemistry and catalytic properties for dioxygen reduction using ferrocene-?substituted cobalt porphyrins" Inorg. Chem. 2014 , 53 , 8600-8609.

•  Nemykin, V. N.; Dudkin, S. V.; Dumoulin, F.; Hirel, C.; Gurek, A. G.; Ahsen, V. "Synthetic approaches to asymmetric phthalocyanines and their analogues" ARKIVOC 2014 , ( i ), 142-204.

•  Dahlby, M. R.; Purchel, A. A.; Solntsev, P. V.; Rohde, G. T.; Zatsikha, Y. V.; Nemykin, V. N. "Synthesis, characterization, redox, and Hg 2+ optical ion sensing properties of ferrocenyl-?containing maleo- and fumaronitrile derivatives" Can. J. Chem. 2014 , 92 , 739-749.

•  Ziegler, C. J.; Chanawanno, K.; Hasheminsasab, A.; Zatsikha, Y. V.; Maligaspe, E.; Nemykin, V. N. "Synthesis, Redox Properties, and Electronic Coupling in the Diferrocene Aza-?dipyrromethene and azaBODIPY Donor-?Acceptor Dyad with Direct Ferrocene-?a-?Pyrrole Bond" Inorg. Chem. 2014 , 53 , 4751-4755.

•  Tamgho, I.-S.; Hasheminasab, A.; Engle, J. T.; Nemykin, V. N.; Ziegler, C. J. "A New Highly Fluorescent and Symmetric Pyrrole-?BF2 Chromophore: BOPHY" J. Am. Chem. Soc. 2014 , 136 , 5623-5626.

•  Yoshimura, A.; Koski, S. R.; Kastern, B. J.; Fuchs, J. M.; Jones, T. N.; Yusubova, R. Y.; Nemykin, V. N.; Zhdankin, V. V. "Hypoiodite-?mediated cyclopropanation of alkenes" Chem. Eur. J. 2014 , 20 , 5895-5898.

•  Varzatskii, O. A.; Penkova, L. V.; Kats, S. V.; Dolganov, A. V.; Vologzhanina, A. V.; Pavlov, A. A.; Novikov, V. V.; Bogomyakov, A. S.; Nemykin, V. N.; Voloshin, Y. Z. "Chloride Ion-?Aided Self-?Assembly of Pseudoclathrochelate Metal Tris-?pyrazoloximates" Inorg. Chem. 2014 , 53 , 3062-3071.

•  Goetsch, W. R.; Solntsev, P. V.; Van Stappen, C.; Purchel, A. A.; Dudkin, S. V.; Nemykin, V. N. "Electron-?Transfer Processes in 3,?4-?Diferrocenylpyrroles: Insight into a Missing Piece of the Polyferrocenyl-?Containing Pyrroles Family" Organometallics 2014 , 33 , 145-157.

•  Nemykin, V. N.; Purchel, A. A.; Spaeth, A. D.; Barybin, M. V. "Probing the Electronic Properties of a Trinuclear Molecular Wire Involving Isocyanoferrocene and Iron(II) Phthalocyanine Motifs" Inorg. Chem. , 2013 , 52 , 11004-11012 ( highlighted on a cover page of October 7 issue ).

•  Dammer, S. J.; Solntsev, P. V.; Sabin, J. R.; Nemykin, V. N. "Synthesis, Characterization, and Electron-Transfer Processes in Indium Ferrocenyl-Containing Porphyrins and Their Fullerene Adducts" Inorg. Chem. 2013 , 52 , 9496-9510.

•  Ziegler, C. J.; Erickson, N. R.; Dahlby, M. R.; Nemykin, V. N. "Magnetic Circular Dichroism Spectroscopy of N-Confused Porphyrin and its Ionized Forms" J. Phys. Chem. A , 2013 , 117 , 11499-11508.

•  Kiprof, P.; Carlson, J. C.; Anderson, D. R.; Nemykin, V. N. "Systematic color tuning of a family of luminescent azole-based organoboron compounds suitable for OLED applications" Dalton Trans. 2013 , 42 , 15120-15132.

•  Vecchi, A.; Galloni, P.; Floris, B.; Nemykin, V. N. "New developments in chemistry of organometallic porphyrins and their analogs". J. Porphyrins Phthalocyanines 2013 , 17 , 165-196 ( highlighted on a cover page of March issue ).

•  Yusubov, M. S.; Svitich, D. Yu.; Yoshimura, A.; Nemykin, V. N.; Zhdankin, V. V. "2-Iodoxybenzoic acid organosulfonates: preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(V) oxidants" Chem. Commun. 2013 , 49 , 11269-11271.

•  Kacharov, A. D.; Yemets, S. V.; Nemykin, V. N.; Kacharova, L. M.; Fokin, A. A.; Krasutsky P. A. " Stereoselectivity of A-ring contraction for 3-oxotriterpenoids" RSC Adv. 2013 , 3 , 19057-19063.

•  Pimkov, I. V.; Nigam, A.; Venna, K.; Fleming, F. F.; Solntsev, P. V.; Nemykin, V. N.; Basu, P. "Dithiolopyranthione Synthesis, Spectroscopy and an Unusual Reactivity with DDQ". J. Heterocyclic Chem. , 2013 , 50 , 879-886.

•  Gao, Y.; Nemykin, V. N. " Modeling of the energies and splitting of the Qx and Qy bands in positional isomers of zinc pyridinoporphyrazines by TDDFT approach: can TDDFT help distinguishing the structural isomers?". J. Mol. Graphics Modeling 2013 , 42 , 73-80.

•  Yusubov, M. S.; Yusubova, R. Y.; Nemykin, V. N.; Zhdankin, V. V. "Preparation and X-ray Structural Study of 1-Arylbenziodoxolones". J. Org. Chem. , 2013 , 78 , 3767-3773.

•  Basu, P.; Kail, B. W.; Adams, A. K.; Nemykin, V. N."Quantitation of the ligand effect in oxo-transfer reactions of dioxo-Mo(VI) tris(pyrazolyl)borate complexes". Dalton Trans. 2013 , 42 , 3071-3081.

•  Lu, Z.; Abbina, S.; Sabin, J. R.; Nemykin, V. N.; Du, G. "Unexpected Formation of Chiral Pincer CNN Nickel Complexes with ß-Diketiminato Type Ligands via C-H Activation: Synthesis, Properties, Structures, and Computational Studies". Inorg. Chem. 2013 , 52 , 1454-1465.

•  Zhu, C.; Yoshimura, A.; Solntsev, P.; Ji, L.; Wei, Y.; Nemykin, V. N.; Zhdankin, V. V. "New highly soluble dimedone-derived iodonium ylides: preparation, X-ray structure, and reaction with carbodiimide leading to oxazole derivatives" Chem. Commun. 2012 , 48 , 10108-10110.

•  Yusubov, M. S.; Yusubova, R. Y.; Nemykin, V. N.; Maskaev, A. V.; Geraskina, M. R.; Kirschning, A.; Zhdankin, V. V. “Potassium 4-iodylbenzenesulfonate: preparation, structure, and application as a reagent for oxidative iodination of arenes”. Eur. J. Org. Chem. 2012 , 5935-5942 .

•  Sabin, J. R.; Varzatskii, O. A.; Voloshin, Y. Z.; Starikova, Z. A.; Novikov, V. V.; Nemykin, V. N. “Insight into the Electronic Structure, Optical Properties, And Redox Behavior of the Hybrid Phthalocyaninoclathrochelates from Experimental and Density Functional Theory Approaches”. Inorg. Chem. , 2012 , 51 , 8362-8372.

•  Gao, Y.; Solntsev, P. V.; Nemykin, V. N. "Comparative electronic structures and UV-vis spectra of tribenzosubporphyrin, tribenzomonoazasubporphyrin, tribenzodiazasubporphyrin, and subphthalocyanine: insight from DFT and TDDFT calculations" J. Mol. Graphics Modelling 2012 , 38 , 369-374.

•  Nemykin, V. N.; Chen, P.; Solntsev, P. V.; Purchel, A. A.; Kadish, K. M. “Characterization of the unusual metal-free, zinc, chloroindium, and ferrocenylindium 5,10,15,20-tetraferrocenylporphyrin anion-radicals by spectroelectrochemical, DFT, and TDDFT approaches”. J. Porphyrins Phthalocyanines 2012 , 16 , 793-801 (invited paper for special issue).

•  Yoshimura, A.; Middleton, K. R.; Zhu, C.; Nemykin, V. N.; Zhdankin, V. V. “Hypoiodite-Mediated Metal-Free Catalytic Aziridination of Alkenes”. Angew. Chem., Int. Ed. , 2012 , 51 , 8059-8062 .

•  Ziegler, C. J.; Nemykin, V. N. “2,5-Diaminothiophene-3,4-dicarbonitrile”. Acta Cryst. E , 2012 , E68 , o2693.

•  Nemykin, V. N.; Sabin, J. R. “Profiling Energetics and Spectroscopic Signatures in Prototropic Tautomers of Asymmetric Phthalocyanine Analogues”. J. Phys. Chem. A 2012 , 116 , 7364-7371.

•  Solntsev, P. V.; Spurgin, K. L.; Sabin, J. R.; Heikal, A. A.; Nemykin, V. N. “Photoinduced Charge Transfer in Short-Distance Ferrocenylsubphthalocyanine Dyads”. Inorg. Chem. 2012 , 51 , 6537-6547.

•  Zhu, C.; Yoshimura, A.; Ji, L.; Wei, Y.; Nemykin, V. N.; Zhdankin, V. V. “Design, Preparation, X-ray Crystal Structure, and Reactivity of o-Alkoxyphenyliodonium Bis(methoxycarbonyl)methanide, a Highly Soluble Carbene Precursor”. Org. Lett. 2012 , 14 , 3170-3173.

•  Vecchi, A.; Gatto, E.; Floris, B.; Conte, V.; Venanzi, M.; Nemykin, V. N.; Galloni, P. “Tetraferrocenylporphyrins as active components of self-assembled monolayers on gold surface”. Chem. Commun. , 2012 , 48, 5145-5147 (invited paper for themed issue).

•  Marcano, D.; Gerasimchuk, N.; Nemykin, V.; Silchenko, S. “Synthesis, Characterization, and Studies of Coordination-Polymers With Isomeric Pyridylcyanoximes: Route to Metal Ribbons With Very Short Tl•••Tl Separations”. Cryst. Growth Design 2012 , 12 , 2877-2889.

•  Ziegler, C. J.; Sabin, J. R.; Geier, G. R.; Nemykin, V. N. “The first TDDFT and MCD studies of free base triarylcorroles: A closer look into solvent-dependent UV-visible absorption”. Chem. Commun. , 2012 , 48 , 4743-4745 (invited paper for themed issue).

•  Nemykin, V. N.; Polshyna, A. E.; Makarova, E. A.; Kobayashi, N.; Lukyanets, E. A. “Unexpected formation of the nickel seco-tribenzoporphyrazine with a tribenzotetraazachlorin-type absorption spectrum”. Chem. Commun. , 2012 , 48 , 3650–3652 (invited paper for themed issue).

•  Ratcliff, J.; Kuduk-Jaworska, J.; Chojnacki, H.; Nemykin, V.; Gerasimchuk, N. “Part 1: Experimental and theoretical studies of 2-cyano-2-isonitroso-N-piperidynylacetamide (HPiPCO), 2-cyano-2-isonitroso-N-morpholylacetamide (HMCO) and their Pt- and Pd-complexes”. Inorg. Chim. Acta., 2012 , 385 , 1-11.

•  Zhu, C.; Yoshimura, A.; Wei, Y.; Nemykin, V. N.; Zhdankin, V. V. “Facile preparation and reactivity of bifunctional ionic liquid-supported hypervalent iodine reagent: a convenient recyclable reagent for catalytic oxidation”. Tetrahedron Lett., 2012 , 53 , 1438-1444.

•  Doboszewski, B.; De Silva, M. J.; Nazarenko, A. Y.; Nemykin, V. N. “3-Deoxy-1,2-di-O-isopropylidene-5-O-tosyl-d-threo-pentofuranose”. Acta Cryst., Section E: Structure Reports Online 2012 , E68 , o1109-o1110.

•  Solntsev, P. V.; Goetsch, W. R.; Nemykin, V. N. “Formation of an Unexpected Organometallic Mercury Compound in a Palladium-Catalyzed Reaction”. Organometallics , 2011 , 30 , 6636-6640.

•  Solntsev, P. V.; Neisen, B. D.; Sabin, J. R.; Gerasimchuk, N. N.; Nemykin, V. N. “Synthesis, characterization, X-ray structure, and mixed-valence states of trans -dichlorotin(IV)-5,10,15,20-tetraferrocenylporphyrin”. J. Porphyrins Phthalocyanines, 2011 , 15 , 612-621 (invited paper for special issue).

•  Nazarenko A. Y.; Nemykin, V. N. “Crystal Data behind Efficient Cesium Recognition: Triphenylcyanoborates of Potassium, Rubidium, and Cesium”. CrystEngComm , 2011 , 13 , 6352-6355.

•  Nemykin, V. N.; Maskaev, A. V.; Geraskina, M. R.; Yusubov, M. S.; Zhdankin, V. V. “Preparation and X-ray crystal study of benziodoxaborole derivatives: new hypervalent iodine heterocycles”. Inorg. Chem. , 2011 , 50 , 11263-11272.

•  Yoshimura, A.; Nemykin, V. N.; Zhdankin, V. V. “o-Alkoxyphenyliminoiodanes: Highly Efficient Reagents for the Catalytic Aziridination of Alkenes and the Metal-Free Amination of Organic Substrates”, Chem. Eur. J. , 2011 , 17 , 10538-10541.

•  Sripothongnak, S.; Ziegler, C. J.; Dahlby, M. R.; Nemykin, V. N. “Controllable and Reversible Inversion of the Electronic Structure in Nickel N-Confused Porphyrin: A Case When MCD Matters”. Inorg. Chem. , 2011 , 50 , 6902-6909 .

•  Rohde, G. T.; Sabin, J. R.; Barrett, C. D.; Nemykin, V. N. “Long-range metal–metal coupling in transition-metal 5,10,15,20-tetraferrocenylporphyrins”. New J. Chem. , 2011 , 35 , 1440-1448.

•  Solntsev, P. V.; Dudkin, S. V.; Sabin, J. R.; Nemykin, V. N. “Electronic Communications in (Z)-Bis(ferrocenyl)ethylenes with Electron-Withdrawing Substituents”. Organometallics, 2011 , 30 , 3037-3046.

•  Yoshimura, A.; Banek, C. T.; Yusubov, M. S.; Nemykin, V. N.; Zhdankin, V. V. “Preparation, X-ray Structure, and Reactivity of 2-Iodylpyridines: Recyclable Hypervalent Iodine(V) Reagents”. J. Org. Chem., 2011 , 76 , 3812-3819.

•  Doboszewski, B.; Nazarenko, A. Y.; Nemykin, V. N. “3'-O-Acetyl-2'-deoxyuridine”. Acta Cryst. 2011 , E67 , o3-o4.

•  Doboszewski, B.; de Toni Uchoa, F.; Nazarenko, A. Y.; Nemykin, V. N. “Crystal structure of 1-deoxy-1-(3-hydroxypropyl)-O-triphenylmethyl- b -D-lyxofuranose, C 27 H 30 O 5 ”. Z. Kristallogr. NCS 2011 , 226 , 61-62.

•  Nemykin, V. N.; Hadt, R. G. “ Interpretation of the UV-Vis spectra of the meso(ferrocenyl)-containing porphyrins using TDDFT approach: is Gouterman's classic four-orbital model still in play?”. J. Phys. Chem. A 2010 , 114 , 12062-12066.

•  Neu, H. M.; Zhdankin, V. V.; Nemykin, V. N. “Binuclear iron(III) phthalocyanine( m -oxodimer)/tetrabutylammonium oxone: a powerful catalytic system for oxidation of hydrocarbons in organic solution”. Tetr. Lett. 2010 , 51 , 6545-6548.

•  Nemykin, V. N.; Rohde, G. T.; Barrett, C. D.; Hadt, R. G.; Sabin, J. R.; Reina, G.; Galloni, P.; Floris, B. "Long-range electronic communication in free-base meso -poly(ferrocenyl)-containing porphyrins". Inorg. Chem. 2010 , 49 , 7497-7509.

• Solntsev, P. V.; Sabin, J. R.; Dammer, S. J.; Gerasimchuk, N. N.; Nemykin, V. N. “Unexpected fluorescence properties  in the axially s -bonded ferrocenyl-containing porphyrin”. Chem. Commun. 2010 , 6581-6583.

• Basu, P.; Nigam, A.; Mogesa, B.; Denti, S.; Nemykin, V. N. “Synthesis, characterization, spectroscopy, electronic and redox properties of a new nickel dithiolene system”. Inorg. Chim. Acta , 2010 , 363 , 2857-2864.

• Yusubov, M. S.; Nemykin, V. N.; Zhdankin, V. V. “Transition metal-mediated oxidations utilizing monomeric iodosyl- and iodylarene species”. Tetrahedron 2010 , 66 , 5745-5752.

•  Yoshimura, A.; Neu, H. M.; Nemykin, V. N.; Zhdankin, V. V. “Metalloporphyrin/Iodine(III)-Cocatalyzed Oxygenation of Aromatic Hydrocarbons”. Adv. Synth. Catal. 2010 , 352 , 1455-1460.

•  Grundt, P.; Douglas, K. A.; Krivogorsky, B.; Nemykin, V. N. “7,9-Dichloro-6H,12H-indolo[2,1-b]quinazoline-6,12-dione”. Acta Cryst. , 2010 , E66 , o1474-o1475.

•  Nemykin, V. N.; Lukyanets, E. A. “Synthesis of substituted phthalocyanines”. ARKIVOC 2010 , i , 136-208.

•  Lukyanets, E. A., Nemykin, V. N. " The key role of peripheral substituents in the chemistry of phthalocyanines and their analogs". J. Porphyrins Phthalocyanines 2010 , 14 , 1 - 40.

•  Doboszewski, B.; da Silva, P. R.; Nazarenko, A. Y.; Nemykin, V. N. “6-[Bis(ethoxycarbonyl)methyl]-6-deoxy-1,2;3,4-di- O -isopropylidene-D-galactopyranose”. Acta Cryst. 2010 , E66 , o3217-o3218.

•  Neu, H. M.; Yusubov, M. S.; Zhdankin, V. V.; Nemykin, V. N. "Binuclear iron(III) phthalocyanine(µ-oxo-dimer)-catalyzed oxygenation of aromatic hydrocarbons with iodosylbenzene sulfate and iodosylbenzene as the oxidants". Adv. Synth. Catal. 2009 , 351 , 3168-3174.

•  Hadt, R. G.; Nemykin, V. N.; Olsen, J. G.; Basu, P. "Comparative calculation of EPR spectral parameters in [Mo V OX 4 ] - , [Mo V OX 5 ] 2- , and [Mo V OX 4 (H 2 O)] - complexes". Phys. Chem. Chem. Phys. 2009 , 11 , 10377-10384.

• Mailyan, A. K.; Geraskin, I. M.; Nemykin, V. N.; Zhdankin, V. V. " Preparation, X-ray Structure, and Oxidative Reactivity of N-(2-Iodylphenyl)tosylamides and 2-Iodylphenyl Tosylate: Iodylarenes Stabilized by Ortho-Substitution with a Sulfonyl Group". J. Org. Chem. 2009 , 74 , 8444-8447.

•  Nemykin, V. N.; Rohde, G. T.; Barrett, C. D.; Hadt, R. G.; Bizzarri, C.; Galloni, P.; Floris, B.; Nowik, I.; Herber, R. H.; Marrani, A. G.; Zanoni, R.; Loim, N. M. " Electron-Transfer Processes in Metal-Free Tetraferrocenylporphyrin. Understanding Internal Interactions To Access Mixed-Valence States Potentially Useful for Quantum Cellular Automata". J. Am. Chem. Soc. 2009 , 131 , 14969-14978.

•  Dorweiler, J. D.; Nemykin, V. N.; Ley, A. N.; Pike, R. D.; Berry, S. M. " Structural and NMR characterization of Sm(III), Eu(III), and Yb(III) Complexes of an amide based polydentate ligand exhibiting Paramagnetic Chemical Exchange Saturation Transfer abilities". Inorg. Chem. 2009 , 48 , 9365-9376.

•  Basu, P.; Nemykin, V. N.; Sengar, R. S. " Substituent Effect on Oxygen Atom Transfer Reactivity from Oxomolybdenum Centers: Synthesis, Structure, Electrochemistry, and Mechanism". Inorg. Chem. 2009 , 48 , 6303-6313.

• Nemykin, V. N.; Koposov, A. Y.; Netzel, B. C.; Yusubov, M. S.; Zhdankin, V. V. " Self-Assembly of Hydroxy(phenyl)iodonium Ions in Acidic Aqueous Solution: Preparation, and X-ray Crystal Structures of Oligomeric Phenyliodine(III) Sulfates". Inorg. Chem. 2009 , 48 , 4908-4917.

• Geraskin, I. M.; Pavlova, O.; Neu, H. M.; Yusubov, M. S.; Nemykin, V. N.; Zhdankin, V. V. " Comparative reactivity of hypervalent iodine oxidants in metalloporphyrin-catalyzed oxygenation of hydrocarbons: iodosylbenzene sulfate and 2-iodylbenzoic acid ester as safe and convenient alternatives to iodosylbenzene". Adv. Synth. Catal. 2009 , 351 , 733-737.

•  Hadt, R. G.; Nemykin, V. N. " Exploring the Ground and Excited State Potential Energy Landscapes of the Mixed-Valence Biferrocenium Complex". Inorg. Chem. 2009 , 48 , 3982-3992.

•  Nemykin, V. N.; Dorweiler, J. D.; Subbotin, R. I. " Ferrocenylbutadiyne'" Acta Cryst., Sec. E: Structure Reports Online 2009 , E65 , m298-m299, m298/1-m298/7.

• Zhdankin, V. V.; Nemykin, V. N.; Karimov, R. R.; Kazhkenov, Z.-G. " Preparation and X-ray crystal structure of 2-iodyl-N,N-dialkylaniline oxides: first entry into the heterocyclic system of benziodoxazole". Chem. Commun. 2008 , 6131-6133 .

• Geraskin, I. M.; Luedtke, M. W.; Neu, H. M.; Nemykin, V. N.; Zhdankin, V. V. " Organic iodine(V) compounds as terminal oxidants in iron(III) phthalocyanine catalyzed oxidation of alcohols". Tetr. Lett. 2008 , 49 , 7410-7412 .

• Ilkun, O. T.; Archibald, S. J.; Barnes, C. L.; Gerasimchuk, N.; Biagioni, R.; Silchenko, S.; Gerasimchuk, O. A.; Nemykin, V. N. " Benz(2-heteroaryl)cyanoximes and their Tl(I) complexes: new room temperature blue emitters". Dalton Trans. 2008 , 5715-5729 .

• Claeys, D. D.; Moonen, K.; Roman, B. I.; Nemykin, V. N.; Zhdankin, V. V.; Waroquier, M.; Van Speybroeck, V.; Stevens, C. V. " Synthesis of Tricyclic Phosphonopyrrolidines via IMDAF: Experimental and Theoretical Investigation of the Observed Stereoselectivity". J. Org. Chem. 2008 , 73 , 7921-7927 .

• Nemykin, V. N.; Galloni, P.; Floris, B.; Barrett, C. D.; Hadt, R. G.; Subbotin, R. I.; Marrani, A. G.; Zanoni, R.; Loim, N. M. " Metal-free and transition-metal tetraferrocenylporphyrins part 1: synthesis, characterization, electronic structure, and conformational flexibility of neutral compounds". Dalton Trans. 2008 , 4233-4246 .

• Herber, R. H.; Nowik, I. Grosland, J. O.; Hadt, R. G..; Nemykin, V. N. " Metal atom dynamics in organometallics: Cyano ferrocenes". J. Organomet. Chem. 2008 , 693 , 1850-1856.

•  Sengar, R. S.; Nemykin, V. N., Basu, P. "Synthesis, Electrochemistry, Geometric and Electronic Structure of Oxo-Molybdenum Compounds Involved in an Oxygen Atom Transferring System". J. Inorg. Biochem. 2008 , 102 , 748-756.

•  Robin, B.; Buell, G.; Kiprof, P.; Nemykin, V. N."3H-1,2-Benzoxaborole-1-spiro-4'-(5-oxa-3a-aza-4-borapyrene)". Acta Cryst. 2008 , E64 , o314-o315, o314/1-o314/8.

•  Pedziwiatr, M.; Kosareff, N. M.; Muller, G.; Koposov, A. Y.; Nemykin, V. N.; Riehl, J. P.; Legendziewicz, J. "Preparation, characterization, and circularly polarized luminiscence of lanthanum and europuim 1,1'-binaphthyl-2,2'-diyl phosphate complexes". J. Alloys Comp. 2008 , 451 , 251-253.

•  Koposov, A. Y.; Nemykin, V. N.; Zhdankin, V. V. "( S )-Methyl 2-(2-iodobenzamido)-propionate". Acta Cryst. 2007 , E63 , o4461.

•  Nemykin, V. N.; Hadt, R. G.; Belosludov, R. V.; Mizuseki, H.; Kawazoe, Y. "Influence of Molecular Geometry, Exchange-Correlation Functional, and Solvent Effects in the Modeling of Vertical Excitation Energies in Phthalocyanines Using TDDFT and PCM-TDDFT Methods: Can Modern Computational Chemistry Methods Explain Experimental Controversies?" J. Phys. Chem. A 2007 , 111 , 12901-12913.

• Nemykin, V. N.; Makarova, E. A.; Grosland, J. O.; Hadt, R. G.; Koposov, A. Y. "Preparation, Characterization, Molecular and Electronic Structures, TDDFT, and TDDFT/PCM Study of the Solvatochromism in Cyanovinylferrocenes". Inorg. Chem. 2007 , 46 , 9591-9601.

• Koposov, A. Y.; Netzel, B. C.; Yusubov M. S; Nemykin, V. N.; Nazarenko, A. Y.; Zhdankin, V. V. "Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO) 3 . SO 3 : stable and water-soluble analog of iodosylbenzene". Eur. J. Org. Chem. 2007 , 4475-4478.

• Stevens, C. V.; Van Meenen, E.; Masschelein, K. G. R.; Eeckhout, Y.; Hooghe, W.; D'Hondt, B.; Nemykin, V. N.; Zhdankin, V. V. "A copper-catalyzed domino radical cyclization route to benzospiro-indolizidinepyrrolidinones". Tetr. Lett. 2007 , 48 , 7108-7111.

• Nemykin, V. N.; Barrett, C. D.; Hadt, R. G.; Subbotin, R. I.; Maximov, A. Y.; Polshin, E. V.; Koposov, A. Y. "Mixed-valence states formation in conformationally flexible metal-free 5,10,15,20-tetraferrocenylporphyrin and 5,10-bisferrocenyl-15,20-bisphenylporphyrin". Dalton Trans. 2007 , 3378-3389.

• Nemykin, V. N.; Koposov, A. Y.; Subbotin, R. I.; Sharma, S. "Preparation and characterization of first optically active rigid phthalocyanine dimers". Tetr. Lett. 2007 , 48 , 5425-5428.

• Nemykin, V. N.; Maximov, A. Y.; Koposov, A. Y. "Mercury-Free Preparation, Characterization, and Molecular Structure of Tricyanovinylferrocene Using an Unusual Reaction between Ferrocene and Tetracyanoethylene". Organometallics 2007 , 26 , 3138-3148.

•  Nemykin, V. N.; Polshyna, A. E.; Borisenkova, S. A.; Strelko, V. V. "Preparation, characterization, and catalytic activity of synthetic carbon-supported (phthalocyaninato)cobalt-containing complexes in dodecane-1-thiol oxidation reaction". J. Mol. Cat. A: Chemical 2007 , 264 , 103-109.

•  Nemykin, V. N.; Olsen, J. G.; Perera, E.; Basu, P. "Synthesis, Molecular and Electronic Structure, and TDDFT and TDDFT-PCM Study of the Solvatochromic Properties of (Me 2 Pipdt)Mo(CO) 4 Complex (Me 2 Pipdt = N,N'-Dimethylpiperazine-2,3-dithione)". Inorg. Chem. 2006 , 45 , 3557 - 3568.

•  Dieltiens, N.; Claeys, D. D.; Zhdankin, V. V.; Nemykin, V. N.; Allaert, B.; Verpoort, F.; Stevens, C. V. "The pyroglutamate hydantoin rearrangement". Eur. J. Org. Chem. 2006 , 2649 – 2660.

• Nemykin, V. N.; Hadt, R. G. "Influence of Hartree-Fock Exchange on the Calculated Moessbauer Isomer Shifts and Quadrupole Splittings in Ferrocene Derivatives Using Density Functional Theory". Inorg. Chem. 2006 , 45 , 8297 - 8307.

• Koposov, A. Y.; Karimov, R. R.; Geraskin, I. M.; Nemykin, V. N.; Zhdankin, V. V. "2-Iodylphenol Ethers: Preparation, X-ray Crystal Structure, and Reactivity of New Hypervalent Iodine(V) Oxidizing Reagents". J. Org. Chem. 2006 , 71 , 8452 - 8458.

• Nemykin, V. N.; Maximov, A. Y.; Barrett, C.; Koposov, A. Y.; McGinn, M.; Loim, N. M.; Breggren, T."Synthesis, spectroscopy, and theoretical modeling of mixed-valence states in polyferrocenyl-containing porphyrins and tetraazaporphyrins". J. Porph. Phthalocyan. 2006 , 10 , 490.

• Nemykin, V. N.; Belosludov, R. V.; Mizuseki, H.; Kawazoe, Y. "Modeling of the vertical excitation energies in the structural isomers of pyridinoporphyrazines and their structural analogues using TDDFT, PCM-TDDFT, ZINDO/S, and PM3 methods". J. Porph. Phthalocyan. 2006 , 10 , 792.

• Nemykin, V. N.; Addei-Maanu, C.; Koposov, A. Y.; Tretyakova, I. N.; Polshyn, E. V. "An investigation of the catalytic degradation of the soluble m -(oxo)dimeric iron phthalocyanine in non-coordinating solvents: spectroscopic and theoretical evidence for the formation of Fe IV -O-Fe IV core". J. Porph. Phthalocyan. 2006 , 10 , 793.

• Ladziata, U.; Koposov, A. Y.; Lo, K. Y.; Willing, J.; Nemykin, V. N.; Zhdankin, V. V. "Synthesis, Structure, and Chemoselective Reactivity of N-(2-Iodylphenyl)acylamides: Hypervalent Iodine Reagents Bearing a Pseudo Six-Membered Ring Scaffold". Angew. Chem. Int. Ed. 2005 , 44 , 7127 -7131.

• Nemykin, V. N.; McGinn, M.; Koposov, A. Y.; Tretyakova, I. N.; Polshin, E. V.; Loim, N. M.; Abramova, N. V. "Accessing of the Mixed-Valence States in the Zinc Meso-Ferrocenylporphyrin: Experimental and Theoretical Data". Ukr. Khim. Zh. 2005 , 69 , 79 – 85.

• McNaughton, R. L.; Mondal, S.; Nemykin, V. N.; Basu, P.; Kirk, M. L. "Oxomolybdenum Tetrathiolates with Sterically Encumbering Ligands: Modeling the Effect of a Protein Matrix on Electronic Structure and Reduction Potentials". Inorg. Chem. 2005 , 44 , 8216-8222.

• Nemykin, V. N.; Basu, P. "Oxygen Atom Transfer Reactivity from a Dioxo-Mo(VI) Complex to Tertiary Phosphines: Synthesis, Characterization, and Structure of Phosphoryl Intermediate Complexes". Inorg. Chem. 2005 , 44 , 7494-7502.

• Koposov, A. Y.; Nemykin, V. N.; Zhdankin, V. V. "Intra- and intermolecular interactions in the solid state structure of 2-iodylbenzenesulfonamides: a heptacoordinated organic iodine(v) compound". New J. Chem. 2005 , 29 , 998-1000.

• Millar, A. J.; Doonan, C. J.; Smith, P. D.; Nemykin, V. N.; Basu, P.; Young, C. G. "Oxygen atom transfer in models for molybdenum enzymes: Isolation and structural, spectroscopic, and computational studies of intermediates in oxygen atom transfer from molybdenum(VI) to phosphorus(III)". Chem. Eur. J. 2005 , 11 , 3255-3267.

• Nazarenko, A. Y.; Nemykin, V. N. "Pentaaquadisodium bis(triphenylcyanoborate) (caesignost)". Acta Cryst. 2005 , E61 , m2317-m2319.

• Nemykin, V. N.; Basu, P. "Energy-Dependent Electrospray Ionization Mass Spectrometric Studies of Mononuclear Metal Carbonyls". Inorg. Chim. Acta 2005 , 358 , 2876-2882.

• Nemykin, V. N.; Laskin, J.; Basu, P. "Isolation, Characterization of an Intermediate in an Oxygen Atom-Transfer Reaction, and the Determination of the Bond Dissociation Energy". J. Am. Chem. Soc. 2004 , 126 , 8604-8605.

• Nemykin, V. N. ; Basu, P. " A bifurcated pathway of oxygen atom transfer reactions from a monooxo molybdenum(VI) complex under electrospray ionization mass spectrometric conditions". Dalton Transactions 2004 , 1928-193 . Research papers prior the faculty position at UMD

• Basu, P.; Nemykin, V. N.; Sengar, R. "Synthesis, spectroscopy, and redox chemistry of encapsulated oxo-Mo(V) centers: implications for pyranopterin-containing molybdoenzymes". Inorg. Chem. 2003 , 42 , 7489-7501.

•  Carrano, C. J.; Chohan, B. S.; Hammes, B. S.; Kail, B. W.; Nemykin, V. N.; Basu, P."Donor Atom Dependent Geometric Isomers in Mononuclear Oxo-Molybdenum(V) Complexes: Implications for Coordinated Endogenous Ligation in Molybdoenzymes". Inorg. Chem. 2003 , 42, 5999-6007.

•  Nemykin, V. N.; Basu, P. "A Comparative Theoretical Investigation of the Vertical Excitation Energies and the Electronic Structure of [Mo V OCl 4 ] - : Influence of Basis Set and Geometry". Inorg. Chem. 2003 , 42 , 4046-4056 .

• Sengar, R. S.; Nemykin, V. N.; Basu, P. "Electronic Properties of para -Substituted Thiophenols and Disulfides from 13 C NMR Spectroscopy and ab initio Calculations: Relations to the Hammett Parameters and Atomic Charges". New J. Chem. 2003 , 27 , 1115-1123 .

• Mytsyk, V. M.; Nemykin, V. N.; Volkov, S. V. "Synthesis of platinum-containing octacarboxylato(phthalocyaninato)zinc". Ukr. Khim. Zh. 2003 , 69 , 3-8.

•  Nemykin, V. N.; Davie, S. R.; Mondal, S.; Rubie, N.; Kirk, M. L.; Somogyi, A.; Basu, P. "An Analogue System Displaying All the Important Processes of the Catalytic Cycles Involving Monooxomolybdenum(VI) and Desoxomolybdenum(IV) Centers". J. Am. Chem. Soc. 2002 , 124 , 756-757.

•  Kail, B.; Nemykin, V. N.; Davie, S. R.; Carrano, C. J.; Hammes, B.; Basu, P. "Synthesis, Characterization, Electrochemistry, Electronic Structure, and Isomerization of Mononuclear Oxo-Molybdenum(V) Complexes: The Serine Gate Hypothesis in the Function of DMSO Reductases". Inorg. Chem. 2002 , 41 , 1281-1291.

•  Kobayashi, N.; Miwa, H.; Nemykin, V. N. "Adjacent versus Opposite Type Di-Aromatic Ring-Fused Phthalocyanine Derivatives: Synthesis, Spectroscopy, Electrochemistry, and Molecular Orbital Calculations". J. Am. Chem. Soc. 2002 , 124 , 8007-8020.

•  Kobayashi, N.; Inagaki, S.; Nemykin, V. N.; Nonomura, T. "A novel hemiporphyrazine comprising three isoindolediimine and three thiadiazole units". Angew. Chem., Int. Ed. 2001 , 40 , 2710-2712.

•  Nemykin, V. N.; Kobayashi, N.; Chernii, V. Y.; Belsky, V. K. "Mössbauer, crystallographic, and density functional theoretical investigation of the electronic structure of bis-ligated low-spin iron (II) phthalocyanines". Eur. J. Inorg. Chem. 2001 , 733-743.

•  Kobayashi, N.; Muranaka, A.; Nemykin, V. N. "The first phthalocyanine-based dimer formed by two pyridine-Pd-pyridine bridges". Tetrahedron Lett. 2001 , 42 , 913-915.

•  Nemykin, V. N.; Kobayashi, N. "A tetraazaporphyrin with an intense, broad near-IR band". Chem. Commun. 2001 , 165-166.

•  Volkov, S. V.; Mytsyk, V. M.; Nemykin, V. N. "Method for production of phthalocyanine and its complexes". UKR ?07 D487/22, C07F19/00 Patent written in Ukrainian. 2001.

•  Nemykin, V. N.; Polshina, A. E.; Kobayashi, N. "Diels-alder reaction of tribenzo[b,g,l]thiopheno[3,4-q]porphyrazine as a new path for porphyrazine core modification". Chem. Lett. 2000 , 1236-1237.

•  Nemykin, V. N.; Myshchyk, V. M. "Synthesis of novel heteronuclear phthalocyanine complexes of zinc and platinum-photosensitizers of "third generation". Ukr. Khim. Zh. (Russ. Ed.) 2000 , 66 , 67-70.

•  Nemykin, V. N.; Mytsyk, V. M.; Volkov, S. V.; Kobayashi, N. "Synthesis and spectroscopic properties of new phthalocyanine complexes with potentially combined photodynamic activity and cytotoxicity for photodynamic therapy". J. Porphyrins Phthalocyanines 2000 , 4 , 551-554.

•  Nemykin, V. N.; Tret'yakova, I. N.; Volkov, S. V.; Li, V. D.; Mekhryakova, N. G.; Kaliya, O. L.; Luk'yanets, E. A. "Synthesis, structure and properties of coordination compounds of iron phthalocyanines and their analogues". Russ. Chem. Rev. 2000 , 69 , 325-346.

•  Nemykin, V. N.; Volkov, S. V. "Mixed-ligand complexes of lanthanides with phthalocyanine and its analogues: synthesis, structure, and spectroscopic properties". Russ. J. Coord. Chem. 2000 , 26 , 436-450.

•  Nemykin, V. N.; Kobayashi, N.; Mytsyk, V. M.; Volkov, S. V. "The solid phase, room-temperature synthesis of metal-free and metallophthalocyanines, particularly of 2,3,9,10,16,17,23,24-octacyanophthalocyanines". Chem. Lett. 2000 , 546-547.

•  Nemykin, V. N.; Polshina, A. E.; Polshin, E. V.; Kobayashi, N. "First direct calculation of the partial quadrupole splitting of ligands for the prediction of Mössbauer spectra parameters in low-spin iron (II) complexes". Mendeleev Commun. 2000 , 54-56.

•  Nemykin, V. N.; Polshina, A. E.; Chernii, V. Y.; Polshin, E. V.; Kobayashi, N. "Synthesis, properties and Mössbauer spectra of bisaxially co-ordinated iron(II) phthalocyanine low-spin complexes: the first semi-quantitative explanation of the influence of the character of axial ligands on the spectral parameters". Dalton 2000 , 1019-1025.

•  Nemykin, V. N.; Kobayashi, N.; Nonomura, T.; Luk'yanets, E. A. "Low symmetrical phthalocyanines having spectroscopic and electrochemical properties characteristic of unexpected accidental S1 state degeneracy and non-planar distortions". Chem. Lett. 2000 , 184-185.

•  Rozhkova, E. A.; Evstigneeva, R. P.; Nemykin, V. N. "Solution coordination chemistry of protohemin IX peptide derivatives". J. Porphyrins Phthalocyanines 1999 , 3 , 691-702.

•  Nemykin, V. N.; Polshina, A. E.; Chernii, V. Y.; Tretyakova, I. N.; Polshin, E. V.; Kobayashi, N. "Method of calculation of the quadrupole splitting in Mössbauer spectra of axially coordinated iron(II) phthalocyanine complexes". Ukr. Khim. Zh. (Russ. Ed.) 1999 , 65 , 103-108.

•  Nemykin, V. N.; Mironyuk, T. I.; Zub, V. Ya.; Volkov, S. V. "Chemochromic properties of mixed-ligand lanthanide phthalocyanine complexes with phthalocyanine cation-radical". Ukr. Khim. Zh. (Russ. Ed.) 1998 , 64 , 75-79.

•  Nemykin, V. N.; Chernii, V. Ya.; Volkov, S. V.; Bundina, N. I.; Kaliya, O. L.; Li, V. D.; Lukyanets, E. A. "Further studies on the oxidation state of iron in m -oxo dimeric phthalocyanine complexes". J. Porphyrins Phthalocyanines 1999 , 3 , 87-98.

•  Kondratenko, N. V.; Tretyakova, I. N.; Luk'yanets, E. A.; Volkov, S. V.; Orlova, R. K.; Nemykin, V. N.; Yagupolskii, L. M. "Synthesis and characterization of polyfluoroalkoxysulfonyl phthalonitriles and corresponding zinc and cobalt phthalocyanines". Dyes Pigments 1999 , 41 , 101-109.

•  Nemykin, V. N.; Chernii, V. Ya.; Pol'shin, E. V.; Kostromina, N. A.; Volkov, S. V. "Electronic and Mössbauer spectra of biaxial complexes of iron (II) phthalocyanine with aliphatic and alicyclic amines". Ukr. Khim. Zh. (Russ. Ed.) 1997 , 63 , 75-84.

•  Nemykin, V. N.; Chernii, V. Ya.; Trachevskii, V. V.; Volkov, S. V. "Proton NMR study of complexation of iron (II) phthalocyanine with aliphatic amines in solutions". Ukr. Khim. Zh. (Russ. Ed.) 1997 , 63 , 3-6.

•  Nemykin, V. N.; Chernii, V. Y.; Volkov, S. V. "Synthesis and characterization of new mixed-ligand lanthanide-phthalocyanine cation radical complexes". J. Chem. Soc., Dalton Trans. 1998 , 2995-3000.

•  Kondratenko, N. V.; Nemykin, V. N.; Lukyanets, E. A.; Kostromina, N. A.; Volkov, S. V.; Yagupolskii, L. M. "The synthesis and properties of some polyfluoroalkoxy substituted phthalocyanines". J. Porphyrins Phthalocyanines 1997 , 1 , 341-347.

•  Nemykin, V. N.; Kostromina, N. A.; Volkov, S. V. "Synthesis and spectroscopic characteristics of some mixed-ligand octaphenyltetraazaporphyrin lutetium complexes". Ukr. Khim. Zh. (Russ. Ed.) 1997 , 63 , 3-6.

•  Evstigneeva, R. P.; Rozhkova, E. A.; Nemykin, V. N.; Voronov, S. A.; Zheltukhina, G. A. "Nonplanar distortion modes for C-aminoacyl derivatives of protohemin IX". Dokl. Akad. Nauk 1997 , 356 , 642-644.

•  Nemykin, V. N.; Voloshin, Y. Z.; Subbotin, N. B. "Method for production of phthalocyanine and its complexes". RU 2061696 C1 19960610 Patent written in Russian. 1996 .

•  Nemykin, V. N.; Subbotin, N. B.; Kostromina, N. A.; Volkov, S. V. "Synthesis and properties of some rare earth 1,2-naphthalocyanines". Ukr. Khim. Zh. (Russ. Ed.) 1995 , 61 , 3-7.

•  Nemykin, V. N.; Tsivadze, A. Yu.; Subbotin, N. B.; Kostromina, N. A.; Volkov, S. V. "Synthesis and spectra of the mixed-ligand monophthalocyanine complexes of rare-earth elements with bidentate oxygen-containing ligands". Russ. J. Coord. Chem. (Transl. of Koord. Khim.) 1996 , 22 , 297-302.

•  Nemykin, V. N.; Kostromina, N. A.; Subbotin, N. B.; Volkov, S. V. "Synthesis and physicochemical properties of highly soluble lanthanide tetra-tert-butyl-2,3-naphthalocyanine complexes". Izv. Akad. Nauk, Ser. Khim. 1996 , 99-102.

•  Nemykin, V. N.; Kostromina, N. A.; Volkov, S. V. "Synthesis and study of chemichromic properties of high-soluble dysprosium bis(tetra-tert-butylnaphthalocyaninate)". Izv. Akad. Nauk, Ser. Khim. 1995 , 1963-1965.

•  Kostromina, N. A.; Chernii, V. Ya.; Nemykin, V. N.; Komarov, I. V. "Complex compounds of phthalocyanineiron(II) with amines". Zh. Neorg. Khim. 1995 , 40 , 1491-1495.

•  Nemykin, V. N.; Subbotin, N. B.; Kostromina, N. A.; Volkov, S. V.; Luk'yanets, E. A. "Synthesis and properties of asymmetrical dinaphthodibenzoporphyrazine complexes with D 2h symmetry of the ligand". Zh. Neorg. Khim. 1995 , 40 , 1183-1188.

•  Nemykin, V. N.; Kostromina, N. A.; Volkov, S. V. "Synthesis of lutetium octaalkylthiotetraazaporphyrins". Izv. Akad. Nauk, Ser. Khim. 1995 , 572-573.

•  Nemykin, V. N.; Subbotin, N. B.; Kostromina, N. A.; Volkov, S. V. "New, non-symmetrical 2:2 phthalocyanines. 1,2,3,4,15,16,17,18-Octaphenyl-9-23(24)-dinitrophthalo- and 1,2,3,4,19,20,21,22-octaphenyldiphthalo-11,29(30)-di-tert-butyldinaphthalocyanine copper complexes". Mendeleev Commun. 1995 , 71-72.

•  Komarov, I. V.; Nemykin, V. N.; Subbotin, N. B. "New selective shift reagents for primary aliphatic amines on the basis of monophthalocyanine lanthanide complexes". Appl. Magn. Reson. 1993 , 4, 377-382.

•  Subbotin, N. B.; Nemykin, V. N.; Voloshin, Y. Z. "A synthesis of novel non-symmetrical phthalocyanines". Mendeleev Commun. 1993 , 121-122.

•  Brusilovets, A. I.; Rusanov, E. B.; Nemykin, V. N. "Reaction of titanium alkoxides with the N,N-bis(trimethylsilyl)amide-N'-tert-butylimide of thiophosphonic acid". Zh. Obshch. Khim. 1989 , 59 , 1893-1894.

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