RESEARCH INTERESTS:
Keywords:
Materials
Chemistry, Inorganic Chemistry, Solid State Chemistry, Oxide Chemistry, Magnetism
and Physical Properties of Solids
Introduction:
Solid State Chemistry encompasses a multitude
of materials with applications as electronic, magnetic, optical and catalytic.
Polycrystalline materials are particularly important because the often
straight forwared sample preparation (often solvent free) and because laboratory
size badges can be scaled up for industrial processing. Oxides provide a wealth
of structures and properties using multivalent cations, ordered and disordered
structures are often very stable and can adapt a large number of structures
while varying oxidation states and thus manipulating the electronic structure
of these solids.
Our research
group focuses on the preparation of novel inorganic solids and the investigation
of their physical properties in an attempt to establish structure - property
relationships. The materials of concern belong to the groups of transition metal
oxides, lanthanide oxides and metal oxychlorides. It is particularly intriguing
to focus on simple solids with, if possible only one paramagnetic ion and otherwise
diamagnetic cations and anions. exhibiting interesting magnetic and physical
properties. The principal tools for the investigation of new solid structures
are powder X-ray diffraction and powder neutron diffraction. The investigation
of physical properties, crystallographic structures and electronic structures
allows the identification of structure-property relationships in solids. A systematic
investigation can enable us to alter materials and their properties in a controlled
fashion and therefore tailor specific materials.
Preparation
of New Materials:
The research includes the preparation of polycrystalline oxides
and oxychlorides using high temperature synthesis as well as low temperature
sol-gel preparation techniques. Single crystals are grown from flux. The synthesis
may be carried out in air, reactive gas atmospheres, inert gases, in vacuum
or in sealed reaction containers. A large variety of synthetic methods can be
employed for the preparation of solids.
Structural
Characterization and Physical Properties:
The principal structural characterization tool is powder diffraction. The diffraction
experiments include powder X-ray diffraction experiments using laboratory X-ray
sources as well as synchrotron sources. Particularly important is the use of
powder neutron diffraction experiments for the determination of oxide structures.
The physical property measurements include magnetic susceptibility and magnetization
measurements, as well as heat capacity and resistivity measurements etc.
Magnetic
Structures:
The determination of magnetic structures are carried out using
powder neutron diffraction. Muon spin relaxation measurements will be used for
short range ordered and glassy magnetic systems. The investigation of magnetic
structures includes long range magnetic ordering at low temperatures for non-frustrated
as well as for frustrated magnetic sublattices. Also the investigation of magnetic
short range ordering is being carried out. Some of these systems show exotic
magnetic ground states due to competing exchange interactions.
last update: August 23, 2015